BJZQH - LEAD-ACID BATTERY

Product Identification

Product ID:LEAD-ACID BATTERY
MSDS Date:01/01/1991
FSC:6140
NIIN:01-032-1326
MSDS Number: BJZQH

Responsible Party
EXIDE CORP GOVERNMENT MARKETING DEPT
RICHMOND, VA 23229-0414
US

Emergency Phone: 818-333-3060

Cage: 1E152

Contractor
EXIDE CORP GOVERNMENT MARKETING DEPT
29414 RICHMOND, VA 23229-0414 US

Telephone: 804-226-0167

Cage: 1E152

Ingredients

LEAD (SARA III)

CAS: 7439-92-1

RTECS: OF7525000

Fraction By Weight: 60%

OSHA PEL 0.05 MG/M3;1910.1025

ACGIH TLV: 0.15 MG/M3;DUST 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB


ANTIMONY (SARA III)

CAS: 7440-36-0

RTECS: CC4025000

Fraction By Weight: 2%

OSHA PEL 0.5 MG/M3

ACGIH TLV: 0.5 MG SB/M3; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS


ARSENIC (SARA III)

CAS: 7440-38-2

RTECS: CG0525000

Fraction By Weight: 0.2%

OSHA PEL 0.5 MG/M3 (AS)

ACGIH TLV: 0.01,A1 MG/M3; 9394

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB


CALCIUM, METAL

CAS: 7440-70-2

RTECS: EV8040000

Fraction By Weight: 0.2%


TIN

CAS: 7440-31-5

RTECS: XP7320000

Fraction By Weight: 0.2%

OSHA PEL 2 MG/M3

ACGIH TLV: 2 MG/M3; 9192


SULFURIC ACID (SARA III)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 10-30%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS


PROPENE POLYMERS (POLYPROPYLENE) BATTERY CASE MATERIALS

CAS: 9003-07-4

RTECS: UD1842000

Fraction By Weight: 5-10%


POYLSTYRENE

CAS: 9003-53-6

RTECS: WL6475000

Fraction By Weight: SEE #7%


STYRENE ACRYLONITRILE COPOLYMER

CAS: 9003-54-7

RTECS: AT6978000

Fraction By Weight: SEE #7%


ACRYLONITRILE BUTADIENE STYRENE COPOLYMER

CAS: 9003-56-9

RTECS: AT6970000

Fraction By Weight: SEE #7%


STYRENE POLYMER WITH 1,3-BUTADIENE

CAS: 9003-55-8

RTECS: WL6478000

Fraction By Weight: SEE #7%


POLYVINYL CHLORIDE RESIN

CAS: 9002-86-2

Fraction By Weight: SEE #7%


POLYCARBONATE

CAS: 24936-68-3

Fraction By Weight: SEE #7%


RUBBER, HARD

Fraction By Weight: SEE #7%


SILICA, CRYSTALLINE - FUSED

CAS: 60676-86-0

RTECS: VV7328000

Fraction By Weight: 10%

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.1 MG/M3 RDUST;9293


SHEET MOLDING COMPOUND (GLASS REINFORCED POLYESTER)

Fraction By Weight: 10%

Hazards

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYES/SKIN: AVOID CONTACT WITH
ELECTROLYTE FROM SPILLED OR BROKEN BATTERY. ELECTROLYTE IS SULFURIC
ACID - CORROSIVE. BATTERY UNIT IS CONSIDERED NON-SPILLABLE AND
CONTAINS ELECTROLYTE IN A NON- CONDUCTI VE POLYSTYRENE CASING WHICH
SHOULD NOT PRESENT UNDO HEALTH OR CONTACT HAZARDS UNLESS CASING
LEAKS OR IS BREACHED.
Explanation of Carcinogenicity:THIS BATTERY CONTAINS TRACE AMOUNTS OF
ARSENIC, A CARCINOGEN BY NTP, IARC, AND OSHA.
Effects of Overexposure:BURNING OR IRRITATION OF EYES/SKIN/ RESPIRATORY
TRACT. OVEREXPOSURE CAN ALSO CAUSE KIDNEY AND LIVER DAMAGE, LOSS OF
APPETITE, CONSTIPATION, DIARRHEA, FATIGUE, DIFFICULTY IN SLEEPING.
CHRONIC EXPOSURE TO SULFURIC ACID/FUMES CAN CAUSE EROSION OF TOOTH
ENAMEL, INFLAMMATION OF NOSE, THROAT AND BRONCHIAL TUBES.
Medical Cond Aggravated by Exposure:EXPOSURE TO MIST MAY AGGRAVATE LUNG
DAMAGE AND PULMONARY CONDITIONS.

First Aid

First Aid:EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES.
GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. INHALATION:
REMOVE TO FRESH AIR.(IF EXPOSURE IS TO LEAD, GARGLE, WASH NOSE AND
LIPS; CONSULT PHYSICIAN) INGESTION: DO NOT INDUCE VOMITING.(ACID)
GIVE MILK TO DRINK. SEEK MEDICAL HELP AT ONCE. IF INGESTION IS OF
LEAD ONLY, INDUCE VOMITING - CONSULT PHYSICIAN.

Fire Fighting

Lower Limits:4.1 HYDROGEN
Upper Limits:74 HYDROGEN
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL AS
APPROPRIATE FOR SURROUNDINGS
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.

Accidental Release

Spill Release Procedures:CONTAIN SPILL USING NON-COMBUSTIBLE MATERIALS
LIKE VERMICULITE, DRY SAND, AND EARTH.
Neutralizing Agent:SODIUM BICARBONATE, SODA ASH OR LIME.

Handling

Handling and Storage Precautions:STORE IN A COOL, DRY, AREA. PROTECT
BATTERY FROM PHYSICAL DAMAGE. DO NOT INCINERATE.
Other Precautions:AVOID CONTACT WITH BATTERY ELEMENTS (LEAD OR ACID
ELECTROLYTE). WASH THOROUGHLY AFTER HANDLING.

Exposure Controls

Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS
PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND
NIOSH-RESPIRATOR SELECTION.
Ventilation:MECHANICAL (GENERAL) VENTILATION IS USUALLY ADEQUATE.
Protective Gloves:ACID RESISTANT GLOVES.
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment:ACID RESISTANT CLOTHING AND BOOTS. EYE WASH
AND SAFETY SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
AVOID CONTACT. DO NOT SMOKE AROUND BATTERIES - HYDROGEN GAS IS
PRODUCED.

Chemical Properties

HCC:N1
Boiling Pt:B.P. Text:203F,95C
Vapor Pres:10
Vapor Density:>1 AIR=1
Spec Gravity:1.23-1.35
pH:<1
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:ELECTROLYTE: CLEAR LIQUID;SHARP PUNGENT ODOR

Stability

Stability Indicator/Materials to Avoid:YES
METALS,STRONG ACIDS,BASES,HALIDES,HALOGENATES, POTASSIUM
NITRATE,PERMANGANATE,PEROXIDES,NASCENT HYDROGEN,REDUCING AGENTS
Stability Condition to Avoid:METALS, ALKALINE CONDITIONS
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, AND
OTHER POSSIBLE BYPRODUCTS SUCH AS ACID MIST AND SULFUR OXIDES AT
VERY HIGH TEMP.

Disposal

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS. ELECTROLYTE ITSELF IS A
HAZARDOUS WASTE (D002/D008) BUT MAY BE NEUTRALIZED WITH SODA ASH OR
SODIUM BICARBONATE AND DI LUTED WITH WATER PRIOR TO SEWER DISPOSAL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.